A Mn(iv)-peroxo complex in the reactions with proton donors.
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DOI: 10.1039/c9dt00649d
Abstract: Protons play an important role in promoting O-O or M-O bond cleavage of metal-peroxo complexes. Treatment of side-on O2-bound [PPN][MnIV(TMSPS3)(O2)] (1, PPN = bis(triphenylphosphine)iminium and TMSPS3H3 = 2,2',2''-trimercapto-3,3',3''-tris(trimethylsilyl)triphenylphosphine) with perchloric acid (HClO4) in the presence… read more here.
Keywords: complex reactions; proton donors; reactions proton; peroxo complex ... See more keywords