Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C-H Functionalization Reactions.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c12198
Abstract: Leveraging congested catalyst scaffolds has emerged as a key strategy for altering innate substrate site-selectivity profiles in C-H functionalization reactions. Similar to enzyme active sites, optimal small molecule catalysts often feature reactive cavities tailored for… read more here.
Keywords: reactive site; site selectivity; complex reactive; functionalization ... See more keywords
Janus and core@shell gold nanorod@Cu2-xS supraparticles: reactive site regulation fabrication, optical/catalytic synergetic effects and enhanced photothermal efficiency/photostability.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc00433b
Abstract: We herein present a reactive site regulation strategy for fabricating well-defined Janus and core@shell gold nanorod-Cu2-xS dual metal-semiconductor plasmonic supraparticles. In addition to enhanced photothermal efficiency and photostability, the nanohybrids possess synergetic photo-thermal and chemical… read more here.
Keywords: reactive site; site regulation; core shell; gold nanorod ... See more keywords