Articles with "reactivity comparisons" as a keyword



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Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with FeV═O and FeIV═O Units.

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Published in 2017 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.7b00448

Abstract: In this report we compare the geometric and electronic structures and reactivities of [FeV(O)]- and [FeIV(O)]2- species supported by the same ancillary nonheme biuret tetraamido macrocyclic ligand (bTAML). Resonance Raman studies show that the Fe═O… read more here.

Keywords: spectroscopic reactivity; comparisons pair; reactivity comparisons; btaml ... See more keywords