Design and reactivity of Ni-complexes using pentadentate neutral-polypyridyl ligands: Possible mimics of NiSOD.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2017.07.005
Abstract: Superoxide plays a key role in cell signaling, but can be cytotoxic within cells unless well regulated by enzymes known as superoxide dismutases (SOD). Nickel superoxide dismutase (NiSOD) catalyzes the disproportion of the harmful superoxide… read more here.
Keywords: reactivity complexes; superoxide dismutation; design reactivity; reactivity ... See more keywords
Catalytic reactivity of the complexes [Pd{(Ph2P)2N( Bu)-P,P´}X2], X = Cl, Br, I, in the Suzuki-Miyaura C−C coupling reaction: Probing effects of the halogeno ligand X− and the ligand's Bu group
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.10.006
Abstract: Abstract The synthesis, as well as the spectroscopic and structural characterization of three analogous palladium(II) complexes, [Pd{(Ph2P)2N(tBu)-κ2P,P´}X2], X = Cl, Br, I, is presented. X-ray crystallography studies revealed a similar square planar PdP2X2 first coordination sphere among… read more here.
Keywords: complexes ph2p; ligand; suzuki miyaura; catalytic reactivity ... See more keywords
Synthesis, Structure, and Catalytic Reactivity of Pd(II) Complexes of Proline and Proline Homologs
Sign Up to like & getrecommendations! Published in 2019 at "Catalysts"
DOI: 10.3390/catal9060515
Abstract: Palladium(II) acetate reacts with proline and proline homologs in acetone/water to yield square planar bis-chelated palladium amino acid complexes. These compounds are all catalytically active with respect to oxidative coupling of olefins and phenylboronic acids.… read more here.
Keywords: synthesis structure; structure catalytic; proline proline; catalytic reactivity ... See more keywords