Synthesis and Reactivity of IrIII Complexes Bearing C-Metalated Pyrazolato Ligands
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DOI: 10.1021/acs.organomet.8b00856
Abstract: A bidentate triazolinylidene-pyrazole chelate ligand was metalated with [IrCp*Cl2]2 to give C,N-chelate complex [4]I. The N1-metalated pyrazole subsequently underwent a rollover metalation to give the complex with C5,C4-metalated pyrazolato ligand [5]. The reactivity of [5]… read more here.
Keywords: reactivity iriii; synthesis reactivity; metalated pyrazolato; reactivity ... See more keywords