Amphoteric reactivity of metal–oxygen complexes in oxidation reactions
Sign Up to like & getrecommendations! Published in 2018 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2018.03.003
Abstract: Abstract Mononuclear metal–oxygen species, such as metal-superoxo, -peroxo, -hydroperoxo and -oxo complexes, are key intermediates involved in dioxygen activation and oxidation reactions catalyzed by a variety of metalloenzymes and their biomimetic compounds. Dioxygen is an… read more here.
Keywords: metal; metal oxygen; oxygen complexes; reactivity metal ... See more keywords
Unusual Reactivity and Metal Affinity of Water-Soluble Dipyrrins.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01834
Abstract: Dipyrrins are a versatile class of organic ligands capable of fluorogenic complexation of metal ions. The primary goal of our study was to evaluate dipyrrins functionalized with ester and amide groups in 2,2'-positions in sensing… read more here.
Keywords: unusual reactivity; water; affinity; reactivity metal ... See more keywords
Synthesis and Reactivity of Metal–Ligand Cooperative Bifunctional Ruthenium Hydride Complexes: Active Catalysts for β-Alkylation of Secondary Alcohols with Primary Alcohols
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00432
Abstract: Three unsymmetrical NNN ligands with a 2-hydroxypyridyl fragment were used to react with RuHCl(PPh3)3(CO), affording the three bidentate ruthenium hydride complexes [(R1-C5H3N-CH2-C5H3N-C5H3N-R2)Ru... read more here.
Keywords: hydride complexes; ruthenium hydride; synthesis reactivity; reactivity metal ... See more keywords