Distinct Reactivity Modes of a Copper Hydride Enabled by an Intramolecular Lewis Acid.
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DOI: 10.1021/jacs.2c02937
Abstract: We disclose a 1,4,7-triazacyclononane (TACN) ligand featuring an appended boron Lewis acid. Metalation with Cu(I) affords a series of tetrahedral complexes including a boron-capped cuprous hydride. We demonstrate distinct reactivity modes as a function of… read more here.
Keywords: lewis acid; reactivity modes; hydride; distinct reactivity ... See more keywords