Structure and Reactivity of Nonporphyrinic Terminal Manganese(IV)-Hydroxide Complexes in the Oxidative Electrophilic Reaction.
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DOI: 10.1021/acs.inorgchem.1c03104
Abstract: High-valent transition metal-hydroxide complexes have been proposed as essential intermediates in biological and synthetic catalytic reactions. In this work, we report the single-crystal X-ray structure and spectroscopic characteristics of a mononuclear nonporphyrinic MnIV-(OH) complex, [MnIV(Me3-TPADP)(OH)(OCH2CH3)]2+… read more here.
Keywords: reactivity nonporphyrinic; structure; structure reactivity; hydroxide complexes ... See more keywords