A Manganese Compound I Model with a High Reactivity in the Oxidation of Organic Substrates and Water.
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DOI: 10.1021/jacs.3c01818
Abstract: A high-valent manganese(IV)-hydroxo porphyrin π-cation radical complex, [Mn(IV)(OH)(Porp+•)(X)]+, was synthesized and characterized spectroscopically. The Mn porphyrin intermediate was highly reactive in alkane hydroxylation and oxygen atom transfer reactions. More importantly, the Mn porphyrin intermediate reacted… read more here.
Keywords: oxidation; reactivity oxidation; compound; water ... See more keywords