Determination of monomer reactivity ratios and thermal properties of poly(GMA-co-MMA) copolymers
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DOI: 10.1007/s00289-020-03123-5
Abstract: Abstract In this study, the free radical copolymerization of glycidyl methacrylate (GMA) and methyl methacrylate (MMA) was investigated for the first time by solution free radical copolymerization in toluene at 80 °C using azobisisobutyronitrile as an… read more here.
Keywords: mma; gma mma; reactivity; reactivity ratios ... See more keywords
Using Triethylborane to Manipulate Reactivity Ratios in Epoxide-Anhydride Copolymerization: Application to the Synthesis of Polyethers with Degradable Ester Functions
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DOI: 10.3390/molecules27020466
Abstract: The anionic ring-opening copolymerization (ROCOP) of epoxides, namely of ethylene oxide (EO), with anhydrides (AH) generally produces strictly alternating copolymers. With triethylborane (TEB)-assisted ROCOP of EO with AH, statistical copolymers of high molar mass including… read more here.
Keywords: using triethylborane; reactivity ratios; triethylborane manipulate; reactivity ... See more keywords
Statistical Copolymers of N–Vinylpyrrolidone and 2–Chloroethyl Vinyl Ether via Radical RAFT Polymerization: Monomer Reactivity Ratios, Thermal Properties, and Kinetics of Thermal Decomposition of the Statistical Copolymers
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DOI: 10.3390/polym15081970
Abstract: The radical statistical copolymerization of N–vinyl pyrrolidone (NVP) and 2–chloroethyl vinyl ether (CEVE) was conducted using the Reversible Addition–Fragmentation chain Transfer (RAFT) polymerization technique, employing [(O–ethylxanthyl)methyl]benzene (CTA-1) and O–ethyl S–(phthalimidylmethyl) xanthate (CTA-2) as the Chain… read more here.
Keywords: reactivity ratios; chloroethyl vinyl; vinyl ether; statistical copolymers ... See more keywords
Bulk Free Radical Terpolymerization of Butyl Acrylate, 2-Methylene-1,3-Dioxepane and Vinyl Acetate: Terpolymer Reactivity Ratio Estimation
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DOI: 10.3390/polym16101330
Abstract: This investigation introduces the first estimation of ternary reactivity ratios for a butyl acrylate (BA), 2-methylene-1,3-dioxepane (MDO), and vinyl acetate (VAc) system at 50 °C, with an aim to develop biodegradable pressure-sensitive adhesives (PSAs). In… read more here.
Keywords: butyl acrylate; reactivity ratios; acrylate methylene; methylene dioxepane ... See more keywords