Metal nitrene-like reactivity of a SiN bond towards CO2
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DOI: 10.1039/c8cc05238g
Abstract: The unusual reactivity of the SiN bond in metallo-iminosilane [DippN = Si(OSiMe3)Ni(Cl)(NHC)2] 1 towards CO2 and cyclohexyl isocyanate (CyNCO) is reported; it reacts with two molar equiv. of CO2 to give the [2+2+2] cycloaddition product… read more here.
Keywords: reactivity sin; metal nitrene; towards co2; sin bond ... See more keywords