Reactivity studies in water on the acid-catalysed dehydration of psicose compared to other ketohexoses into 5-hydroxymethylfurfural.
Sign Up to like & getrecommendations! Published in 2017 at "Carbohydrate research"
DOI: 10.1016/j.carres.2017.04.009
Abstract: The conversion of the four possible ketohexoses (fructose, tagatose, sorbose and psicose) into 5-hydroxymethylfurfural (HMF) was explored in water using sulphuric acid as the catalyst (33 mM H2SO4, 120 °C). Significant differences in reactivity were observed and tagatose… read more here.
Keywords: water; conversion min; reactivity; reactivity studies ... See more keywords
Reactivity studies on aminotroponiminatogermylene stabilized ruthenium(II) complexes
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.02.006
Abstract: Abstract Aminotroponiminatogermylene stabilized ruthenium(II) complexes and reactivity studies on N-heterocyclic germylene stabilized ruthenium(II) complexes were not known. Therefore, this work reports the synthesis of aminotroponiminatogermylene stabilized ruthenium(II) complexes [L1Ge(X){RuCl2(Y)}] (L1 = (i-Bu)2ATI; (ATI = aminotroponiminate), X = Cl 1, NC4H4… read more here.
Keywords: reactivity studies; stabilized ruthenium; ruthenium; ruthenium complexes ... See more keywords
A pyramidal Tin(II) dication and its reactivity studies
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.02.019
Abstract: Abstract An acyclic flexible bis(α-iminopyridine) ligand has been employed for the stabilization of chlorostannyliumylidene and a tin(II) dication. The syntheses involve the abstraction of chloride from the tin dichloride precursor using trimethylsilyl trifluoromethane sulfonate. The… read more here.
Keywords: reactivity studies; dication; tin dication; pyramidal tin ... See more keywords
Synthesis and Reactivity Studies of a [Cp*Rh] Complex Supported by a Methylene-Bridged Hybrid Phosphine-Imine Ligand.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of organometallic chemistry"
DOI: 10.1016/j.jorganchem.2020.121294
Abstract: [Cp*Rh] complexes (Cp* = η 5-pentamethylcyclopentadienyl) supported by bidentate chelating ligands are useful in studies of redox chemistry and catalysis, but little information is available for derivatives bearing "hybrid" [P,N] chelates. Here, the preparation, structural… read more here.
Keywords: chemistry; reactivity; methylene; reactivity studies ... See more keywords
Modeling the DFT structural and reactivity studies of a pyrimidine -6-carboxylate derivative with reference to its wavefunction-dependent, MD simulations and evaluation for potential antimicrobial activity
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2021.130397
Abstract: Abstract Spectroscopic, electronic and chemical properties and molecular docking simulations of ethyl-2-(4-ethoxybenzylidene)-7-methyl-3-oxo-5-(4-benzyloxyphenyl)-2,3-dihydro-5H-[1,3] thiazolo [3,2-a]pyrimidine-6-carboxylate (EMTP) have been extensively studied and discussed on DFT calculations. Using potential energy scans for various rotable bonds to obtain the… read more here.
Keywords: reactivity studies; structural reactivity; pyrimidine carboxylate; modeling dft ... See more keywords
Reactivity Studies of Cationic Au(III) Difluorides Supported by N Ligands
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00429
Abstract: The reactivity of difluoro Au(III) cations supported by pyridine or imidazole ligands is reported. The Au(III)–F bond is found to be susceptible to metathesis by TMS reagents and reagents bearing a... read more here.
Keywords: cationic iii; studies cationic; iii difluorides; reactivity ... See more keywords
Reactivity studies of an imine-functionalised phosphaalkene; unusual electrostatic and supramolecular stabilisation of a σ2λ3-phosphorus motif via hydrogen bonding.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt01607k
Abstract: A P[double bond, length as m-dash]C heavy-alkene analogue that is unreactive towards the addition of strong acids on its double-bond is presented; instead, a strategically located imine nitrogen on the periphery forms protonated adducts displaying… read more here.
Keywords: studies imine; hydrogen; stabilisation; reactivity studies ... See more keywords