Stereoselective addition of Grignard reagents to sulfinimines derived from tartrate diol (threitol): Generation of chiral building blocks for the collective total synthesis of lentiginosine, conhydrine and methyldihydropalustramate
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DOI: 10.1016/j.tet.2019.130496
Abstract: Abstract A systematic investigation of the addition of Grignard reagents to sulfinimines derived from tartaric acid diol was undertaken. It was observed that the chirality of the inherent tartrate moiety influences the diastereoselectivity of the… read more here.
Keywords: sulfinimines derived; addition grignard; building blocks; collective total ... See more keywords