Hypervalent Iodine(III) Reagents with Transferable Primary Amines: Structure and Reactivity of the Electrophilic α-Amination on Stabilized Enolates.
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DOI: 10.1021/acs.orglett.1c04312
Abstract: A new family of hypervalent iodine reagents containing transferable primary amine groups is described. Benziodoxolone-based reagents were synthesized on the gram-scale through operationally simple reactions in up to quantitative yields. These bench-stable solids were characterized… read more here.
Keywords: amination; reagents transferable; iodine iii; transferable primary ... See more keywords