Cu(I)/Chiral Vanadium Complex Cooperatively Catalyzed Asymmetric Sulfonation/Rearrangement of Alkenylfurans.
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DOI: 10.1021/acs.orglett.2c03304
Abstract: The asymmetric three-component rearrangement of alkenylfurans with various sulfonyl chlorides and anilines is developed via copper(I) and chiral vanadium cooperative catalysis, providing a facile access to a broad spectrum of sulfonyl-functionalized 4-aminocyclopentenones in high yields… read more here.
Keywords: rearrangement alkenylfurans; chiral vanadium; complex cooperatively; vanadium complex ... See more keywords