Switchable Smiles Rearrangement for Enantioselective O-Aryl Amination.
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DOI: 10.1021/acs.orglett.9b01848
Abstract: Asymmetric assembly of atropisomeric anilines from abundant and readily available precursors is one of the most challenging but valuable processes in organic synthesis. The use of highly efficient Smiles rearrangement to accomplish switchable enantioselective amination… read more here.
Keywords: switchable smiles; enantioselective aryl; aryl amination; amination ... See more keywords