One-pot Mukaiyama type carbon-Ferrier rearrangement of glycals: Application in the synthesis of chromanone 3-C-glycosides.
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DOI: 10.1016/j.carres.2016.11.018
Abstract: One-pot carbon-Ferrier rearrangement of glycals with unactivated aryl methyl ketones has been developed under mild Silyl triflate catalysis. Keto methyl group of various aryl methyl ketones without being converted into silyl enol ether could directly… read more here.
Keywords: ferrier rearrangement; chromanone glycosides; rearrangement glycals; one pot ... See more keywords