Sensitive Assays by Nucleophile-Induced Rearrangement of Photoactivated Diarylethenes.
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DOI: 10.1021/jacs.8b02982
Abstract: Upon light-induced isomerization, diarylethenes (DAEs) equipped with reactive aldehyde moieties rearrange selectively in the presence of amines, accompanied by decoloration. In a comprehensive study, the probe structure was optimized with regard to its inherent reactivity… read more here.
Keywords: photoactivated diarylethenes; assays nucleophile; sensitive assays; rearrangement photoactivated ... See more keywords