C-H Fluoroalkylsulfinylation/Intramolecular Rearrangement for Precise Synthesis of Fluoroalkyl Sulfoxides.
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DOI: 10.1021/acs.orglett.2c01151
Abstract: An efficient methodology to access various fluoroalkyl sulfoxides bearing ortho/para-functionalized amine scaffolds from arylhydroxylamines is described. The transformation was featured with new electrophilic trifluoromethylthiolated reagents, good functional group tolerance, and late-stage modification of complex bioactive… read more here.
Keywords: fluoroalkyl; fluoroalkyl sulfoxides; fluoroalkylsulfinylation intramolecular; intramolecular rearrangement ... See more keywords