Enantioselective Total Synthesis of (-)-Hamigeran F and Its Rearrangement Product.
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DOI: 10.1021/acs.orglett.2c01997
Abstract: Herein, we report the first enantioselective total synthesis of the highly complex hamigeran diterpenoid (-)-hamigeran F and its rearrangement product. The synthetic strategy features key steps of asymmetric hydrogenation, Horner-Wadsworth-Emmons olefination, and intramolecular Friedel-Crafts acylation… read more here.
Keywords: rearrangement product; hamigeran rearrangement; enantioselective total; total synthesis ... See more keywords