Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes via chirality transfer from silicon to carbon
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DOI: 10.1039/c9ra05482k
Abstract: Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes has been developed involving Si-to-C chirality transfer, which is diastereoselective without loss of enantiomeric excess. read more here.
Keywords: chirality transfer; rearrangement silyl; asymmetric retro; brook rearrangement ... See more keywords