The Baldwin Rearrangement: Synthesis of 2‐Acylaziridines
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201700920
Abstract: The Baldwin rearrangement is a thermally induced ring contraction of 4-isoxazolines into 2-acylaziridines. The reaction yields highly strained nitrogen-containing three-membered-ring compounds from readily available five-membered N-O heterocycles. Diversely substituted isoxazolines are directly transformed into a… read more here.
Keywords: chemistry; rearrangement synthesis; synthesis acylaziridines; baldwin rearrangement ... See more keywords
Chiral Primary Amine Catalyzed Enantioselective Tandem Reactions Based on Heyns Rearrangement: Synthesis of α-Tertiary Amino Ketones.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00724
Abstract: Herein, we disclose a new catalytic asymmetric tandem reaction based on the Heyns rearrangement for the synthesis of chiral α-amino ketones with readily available substrates. The rearrangement is different from the Heyns rearrangement in that… read more here.
Keywords: based heyns; heyns rearrangement; amino ketones; chiral primary ... See more keywords