Articles with "rearrangements carbocations" as a keyword



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Chemical synthesis of terpenoids with participation of cyclizations plus rearrangements of carbocations: a current overview

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Published in 2019 at "Phytochemistry Reviews"

DOI: 10.1007/s11101-019-09646-8

Abstract: Many terpenoids are biosynthesized after a cascade of cyclizations and rearrangements of carbocations mediated by terpenoid synthases, as exemplified in the biosynthesis of lanosterol. Although several reports of organisms or purified enzymes catalyzing this cascade… read more here.

Keywords: participation; rearrangements carbocations; terpenoids participation; participation cyclizations ... See more keywords