Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds.
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DOI: 10.1021/acs.accounts.1c00664
Abstract: Conspectusα-Diazocarbonyl compounds serve as nucleophiles, dipoles, carbene precursors, and rare electrophiles, enabling a vast array of organic transformations under the influence of metal catalysts. Among them, rearrangement processes are attractive and provide straightforward and efficient… read more here.
Keywords: dioxide metal; substituted diazo; group; diazocarbonyl compounds ... See more keywords