Beyond Radical Rebound: Methane Oxidation to Methanol Catalyzed by Iron Species in Metal-Organic Framework Nodes.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c04766
Abstract: Recent work has exploited the ability of metal-organic frameworks (MOFs) to isolate Fe sites that mimic the structures of sites in enzymes that catalyze selective oxidations at low temperatures, opening new pathways for the valorization… read more here.
Keywords: radical rebound; beyond radical; rebound; metal organic ... See more keywords
A catalytic fluoride-rebound mechanism for C(sp3)-CF3 bond formation
Sign Up to like & getrecommendations! Published in 2017 at "Science"
DOI: 10.1126/science.aan1411
Abstract: Trifluoromethylation via broken C-F bonds Trifluoromethyl substituents are widely used in pharmaceutical research to tune the properties of drug candidates. Generally, they are introduced intact through the formation of carbon-carbon bonds. Levin et al. discovered… read more here.
Keywords: mechanism; bond; fluoride rebound; sp3 cf3 ... See more keywords