Nitroxide polymer brushes as efficient and recoverable catalysts for the selective oxidation of primary alcohols to aldehydes
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Applied Polymer Science"
DOI: 10.1002/app.44365
Abstract: 2,2,6,6-Tetramethylpiperidinyloxyl (TEMPO)-containing polymer brushes were grafted onto crosslinked polystyrene microspheres via surface-initiated activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP) of 2,2,6,6-tetramethyl-4-piperidyl methacrylate, followed by an oxidation process with 3-chloroperoxybenzoic acid as… read more here.
Keywords: oxidation; microscopy; recoverable catalysts; nitroxide polymer ... See more keywords
Facile Synthesis of Magnetically Recoverable Pd and Ru Catalysts for 4-Nitrophenol Reduction: Identifying Key Factors
Sign Up to like & getrecommendations! Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.8b02382
Abstract: This paper reports the development of robust Pd- and Ru-containing magnetically recoverable catalysts in a one-pot procedure using commercially available, branched polyethyleneimine (PEI) as capping and reducing agent. For both catalytic metals, ∼3 nm nanoparticles… read more here.
Keywords: recoverable catalysts; facile synthesis; synthesis magnetically; magnetically recoverable ... See more keywords