Articles with "redox activity" as a keyword



Redox Activity of Electronically Excited Phosphorus-Corroles with Axial Chalcogenation.

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Published in 2025 at "ChemPlusChem"

DOI: 10.1002/cplu.202500137

Abstract: Quest for visible-light absorbing metal-free corroles is of increased research interest for both electrocatalytic and photocatalytic applications among others. To this direction, phosphorus corrole (PC) and its functional derivatives hold great potential. In this study,… read more here.

Keywords: equation; redox; equation equation; chalcogenation ... See more keywords
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Redox Active Cerium Oxide Nanoparticles: Current Status and Burning Issues.

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Published in 2021 at "Small"

DOI: 10.1002/smll.202102342

Abstract: Research on cerium oxide nanoparticles (nanoceria) has captivated the scientific community due to their unique physical and chemical properties, such as redox activity and oxygen buffering capacity, which made them available for many technical applications,… read more here.

Keywords: research; cerium oxide; oxide nanoparticles; redox activity ... See more keywords
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Bilirubin Links Heme Metabolism to Neuroprotection by Scavenging Superoxide.

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Published in 2019 at "Cell chemical biology"

DOI: 10.1016/j.chembiol.2019.07.006

Abstract: Bilirubin is one of the most frequently measured metabolites in medicine, yet its physiologic roles remain unclear. Bilirubin can act as an antioxidant in vitro, but whether its redox activity is physiologically relevant is unclear because… read more here.

Keywords: links heme; bilirubin links; heme metabolism; redox activity ... See more keywords

DNA repair enzyme APE1 from evolutionarily ancient Hydra reveals redox activity exclusively found in mammalian APE1.

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Published in 2017 at "DNA repair"

DOI: 10.1016/j.dnarep.2017.09.005

Abstract: Only mammalian apurinic/apyrimidinic endonuclease1 (APE1) has been reported to possess both DNA repair and redox activities. C terminal of the protein is required for base excision repair, while the redox activity resides in the N… read more here.

Keywords: mammalian ape1; redox activity; dna repair; repair ... See more keywords
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Metal-centered redox activity in a polymeric Cobalt(II) complex of a sterically hindered salen type ligand

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Published in 2020 at "Electrochimica Acta"

DOI: 10.1016/j.electacta.2020.136496

Abstract: Abstract This paper reports on the peculiarities of the metal-centered redox activity in a polymeric cobalt(II) complex of a sterically hindered tetradentate N2O2 Schiff base (salen type) ligand. A Co(III)/Co(II) redox process in the polymer… read more here.

Keywords: redox activity; redox; sterically hindered; metal centered ... See more keywords

Catalytic and redox activity of nucleic acids at mercury electrodes: Roles of nucleobase residues

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Published in 2020 at "Journal of Electroanalytical Chemistry"

DOI: 10.1016/j.jelechem.2019.113812

Abstract: Abstract Using a series of specifically designed oligonucleotides we have identified adenine and cytosine nucleobases as residues involved in catalytic hydrogen evolution reaction (CHER) of nucleic acids at the hanging mercury drop electrode (HMDE). Due… read more here.

Keywords: nucleic acids; activity nucleic; catalytic redox; redox activity ... See more keywords

Tailoring Anionic Redox Activity in a P2-Type Sodium Layered Oxide Cathode via Cu Substitution.

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Published in 2022 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.2c02858

Abstract: Na-ion cathode materials cycling at high voltages with long cycling life and high capacity are of imminent need for developing future high-energy Na-ion batteries. However, the irreversible anionic redox activity of Na-ion layered cathode materials… read more here.

Keywords: anionic redox; activity; layered oxide; cathode ... See more keywords

Lattice Modulation on Air-Stable Fe-Based Prelithiation Materials with High Capacity via Triggering Anionic Redox Activity.

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Published in 2025 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.4c21194

Abstract: Li5FeO4 (LFO) is a leading candidate for cathode prelithiation due to its ability to engage in both anionic and cationic redox processes, offering substantial capacity potential. However, the practical implementation of LFO is hampered by… read more here.

Keywords: redox; capacity; air; redox activity ... See more keywords

A zeolitic vanadotungstate family with structural diversity and ultrahigh porosity for catalysis

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Published in 2018 at "Nature Communications"

DOI: 10.1038/s41467-018-06274-2

Abstract: Design of the structure and composition of crystalline microporous inorganic oxides is of great importance in catalysis. Developing new zeolites is one approach towards this design because of the tunable pore system and high thermal… read more here.

Keywords: porosity; diversity; redox activity; catalysis ... See more keywords
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Ligand field-actuated redox-activity of acetylacetonate†

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Published in 2020 at "Chemical Science"

DOI: 10.1039/d0sc01836h

Abstract: The quest for simple ligands that enable multi-electron metal–ligand redox chemistry is driven by a desire to replace noble metals in catalysis and to discover novel chemical reactivity. The vast majority of simple ligand systems… read more here.

Keywords: ligand field; ligand; redox activity;

Rich redox-activity and solvatochromism in a family of heteroleptic cobalt complexes.

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Published in 2021 at "Dalton transactions"

DOI: 10.1039/d1dt03327a

Abstract: The combination of redox-active metals with redox-active ligands can lead to interesting charge transfer behaviours, including valence tautomerism and solvatochromism. With the aim of investigating a relatively underexplored redox-active metal/redox-active ligand combination, complexes [CoII(acac)2(X-BIAN)] (acac-… read more here.

Keywords: solvatochromism; redox activity; charge; redox active ... See more keywords