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Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115119
Abstract: Abstract The pincer ligand PNNH contains pyridine with its ortho carbons bearing one tBu2PCH2 donor and one pyrazole donor. A DFT study of the energies and structures of (PNNH)Mn(CO)n(NOx) (n = 0–2, x = 0–3)…
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Keywords:
nox;
deoxygenation;
nox complexes;
redox cascade ... See more keywords
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Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b03530
Abstract: We report a direct β-alkylation of ketones and aldehydes with simple alkyl bromides through a Pd-catalyzed redox-cascade strategy. The use of a Cu cocatalyst is important for improved efficiency. The reaction is redox-neutral, without the…
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Keywords:
ketones aldehydes;
alkylation;
catalyzed redox;
redox cascade ... See more keywords