Redox-Controlled Fluorescent Nanoswitch Based on Reversible Disulfide and Its Application in Butyrylcholinesterase Activity Assay.
Sign Up to like & getrecommendations! Published in 2018 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.7b02976
Abstract: Butyrylcholinesterase (BChE) mainly contributing to plasma cholinesterase activity is an important indicator for routinely diagnosing liver function and organophosphorus poisoning in clinical diagnosis, but its current assays are scarce and frequently suffer from some significant… read more here.
Keywords: fluorescence; chemistry; redox; activity ... See more keywords
Redox-Controlled and Reversible N-N Bond Forming and Splitting with an IronIV Terminal Imido Ligand.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c01509
Abstract: Oxidation of the low-spin FeIV imido complex [{(tBupyrr)2py}Fe═NAd] (1) ((tBupyrr)2py2- = 2,6-bis(3,5-di-tert-butyl-pyrrolyl)pyridine, Ad = 1-adamantyl) with AgOAc or AgNO3 promotes reductive N-N bond coupling of the former imido nitrogen with a pyrrole nitrogen to form… read more here.
Keywords: imido; bond; tbupyrr; imido ligand ... See more keywords
Redox-Controlled Shunts in a Synthetic Chemical Reaction Cycle
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c00985
Abstract: Shunts, alternative pathways in chemical reaction networks (CRNs), are ubiquitous in nature, enabling adaptability to external and internal stimuli. We introduce a CRN in which the recovery of Michael-accepting species is driven by oxidation chemistry.… read more here.
Keywords: cycle; chemical reaction; chemistry; redox controlled ... See more keywords
Redox-controlled hybridization of helical foldamers.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc02498k
Abstract: Tetrathiafulvalene redox units were grafted at both extremities of an oligopyridine-dicarboxamide foldamer through a straightforward copper-catalyzed azide-alkyne cycloaddition. The present work demonstrates that the hybridization equilibrium of foldamers can be tuned through redox stimulations. read more here.
Keywords: hybridization helical; helical foldamers; controlled hybridization; redox controlled ... See more keywords
Redox-controlled conductance of polyoxometalate molecular junctions.
Sign Up to like & getrecommendations! Published in 2022 at "Nanoscale"
DOI: 10.1039/d2nr03457c
Abstract: We demonstrate the reversible in situ photoreduction of molecular junctions of a phosphomolybdate [PMo12O40]3- monolayer self-assembled on flat gold electrodes, connected by the tip of a conductive atomic force microscope. The conductance of the one… read more here.
Keywords: conductance; current voltage; redox controlled; molecular orbital ... See more keywords
Redox-controlled epitaxy and magnetism of oxide heterointerfaces: EuO/SrTiO3
Sign Up to like & getrecommendations! Published in 2019 at "Physical Review Materials"
DOI: 10.1103/physrevmaterials.3.061401
Abstract: We demonstrate a novel route to prepare thin films of the ferromagnetic insulator Europium monoxide. Key is a redox-controlled interface reaction between metallic Eu and the substrate SrTiO$_3$ as the supplier of oxygen. The process… read more here.
Keywords: controlled epitaxy; heterointerfaces euo; epitaxy magnetism; oxide heterointerfaces ... See more keywords