Redox effects of low-spin Ru(ii/iii) on slow magnetic relaxation of Ru-Mn(iii) 1D cyanide-bridged complexes.
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DOI: 10.1039/c7dt01218g
Abstract: A new one-dimensional cyanide-bridged complex [MnIII(salphen)RuII(DMAP)4(CN)2](PF6) (1) and its oxidized derivative [MnIII(salphen)RuIII(DMAP)4(CN)2](PF6)2 (2) have been synthesized and fully characterized. Magnetic measurements showed that 1 shows simple paramagnetism but 2 shows intrachain ferromagnetic interaction with slow… read more here.
Keywords: redox effects; slow magnetic; magnetic relaxation; cyanide bridged ... See more keywords