Role of Redox-Inactive Transition-Metals in the Behavior of Cation-Disordered Rocksalt Cathodes.
Sign Up to like & getrecommendations! Published in 2020 at "Small"
DOI: 10.1002/smll.202000656
Abstract: Owing to the capacity boost from oxygen redox activities, Li-rich cation-disordered rocksalts (LRCDRS) represent a new class of promising high-energy Li-ion battery cathode materials. Redox-inactive transition-metal (TM) cations, typically d0 TM, are essential in the… read more here.
Keywords: oxygen; cation disordered; redox; inactive transition ... See more keywords
Role of redox-inactive metals in controlling the redox potential of heterometallic manganese–oxido clusters
Sign Up to like & getrecommendations! Published in 2021 at "Photosynthesis Research"
DOI: 10.1007/s11120-021-00846-y
Abstract: Photosystem II (PSII) contains Ca2+, which is essential to the oxygen-evolving activity of the catalytic Mn4CaO5 complex. Replacement of Ca2+ with other redox-inactive metals results in a loss/decrease of oxygen-evolving activity. To investigate the role… read more here.
Keywords: inactive metals; controlling redox; redox inactive; role redox ... See more keywords
The Role of Redox-Inactive Metals in Modulating the Redox Potential of the Mn4CaO4 Model Complex.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00243
Abstract: Photosynthetic oxygen-evolving center (OEC), the "engine of life", is a unique Mn4CaO5 cluster catalyzing the water oxidation. The role of redox-inactive component Ca2+, which can only be functionally replaced by Sr2+ in a biological environment,… read more here.
Keywords: model complex; redox potential; redox inactive; model ... See more keywords
Uncoupled Redox-Inactive Lewis Acids in the Secondary Coordination Sphere Entice Ligand-Based Nitrite Reduction.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00032
Abstract: Metal complexes composed of redox-active pyridinediimine (PDI) ligands are capable of forming ligand-centered radicals. In this Forum article, we demonstrate that integration of these types of redox-active sites with bioinspired secondary coordination sphere motifs produce… read more here.
Keywords: coordination sphere; ligand based; secondary coordination; redox inactive ... See more keywords
Redox-Inactive Metal Cations Modulate the Reduction Potential of the Uranyl Ion in Macrocyclic Complexes.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b11903
Abstract: Capture and activation of the water-soluble uranyl dication (UO22+) remains a challenging problem, as few rational approaches are available for modulating the reactivity of this species. Here, we report the divergent synthesis of heterobimetallic complexes… read more here.
Keywords: inactive metal; reduction potential; redox inactive;