Redox-Induced Interconversion of Two Au8 Nanoclusters: the Mechanism and the Structure-Bond Dissociation Activity Correlations.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c03828
Abstract: The interconversion of atomically precise nanoclusters represents an excellent platform to understand the structural correlations of nanomaterials at the atomic level. Herein, density functional theory calculations were performed to elucidate the mechanism of the redox-induced… read more here.
Keywords: au8; au8 dppp; bond; redox induced ... See more keywords
Cobalt complexes with hemilabile o-iminobenzoquinonate ligands: a novel example of redox-induced electron transfer.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt02733a
Abstract: The tetracoordinated square-planar CoIII complex (imSQC(O)Ph)CoIII(APC(O)Ph) (1) bearing a radical anion and the closed-shell o-amidophenolate forms of the functionalized o-aminophenol H2LC(O)Ph were synthesized. The intermediate spin state (SCo = 1) CoIII center was found for… read more here.
Keywords: redox induced; redox; example; electron transfer ... See more keywords
Chemical redox-induced chiroptical switching of supramolecular assemblies of viologens
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d1ra08984f
Abstract: A chiral supramolecular assembly exhibiting redox-induced changes in its chiroptical properties was prepared using viologen-modified glutamide (G-V2+) derivatives. Achiral viologen moieties in the G-V2+ assembly were chirally orientated by glutamide groups, affording a unique orange-colored… read more here.
Keywords: chemical redox; redox; induced chiroptical; chiroptical switching ... See more keywords
Redox-induced reversible [2 + 2] cycloaddition of an etheno-fused diporphyrin†
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DOI: 10.1039/d1sc00438g
Abstract: 3,5-Ethenoporphyrin is a π-extended porphyrin containing a fused ethene unit between the meso- and β-positions, exhibiting unique contribution of macrocyclic antiaromaticity. We have recently reported that its analogue, etheno-fused diporphyrin, underwent thermal [2 + 2]… read more here.
Keywords: fused diporphyrin; etheno fused; cycloaddition; redox induced ... See more keywords
pH and Redox Induced Color Changes in Protein Crystals Suffused with Dyes
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DOI: 10.3390/cryst9030126
Abstract: Protein crystals, otherwise usually colorless, can be stained a variety of hues by saturating them with dyes, by diffusion from the mother liquor or co-crystallization. The colors assumed by dyes are a function of chemical… read more here.
Keywords: protein crystals; redox induced; color changes; color ... See more keywords