Solvent-Induced Redox Isomerism of Cobalt Complexes with Redox-Active Bisguanidine Ligands.
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DOI: 10.1021/acs.inorgchem.1c03983
Abstract: Redox-isomeric coordination compounds, in which the magnetic and optical properties could be varied by a stimulated intramolecular electron transfer between the metal and a redox-active ligand, are of interest for several applications in catalysis and… read more here.
Keywords: active bisguanidine; redox active; chemistry; cobalt complexes ... See more keywords
On the Dynamic Behavior of Pacman Phosphanes─A Case of Cooperativity and Redox Isomerism.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00481
Abstract: In solution, the Pacman chlorophosphane (2Cl) shows fast exchange of the endo/exo-orientation of the two P-Cl bonds in the molecule featuring cooperativity. Experimental and quantum mechanical investigations of the inversion on the phosphorus(III) centers reveal… read more here.
Keywords: behavior pacman; dynamic behavior; redox isomerism; cooperativity ... See more keywords