Phase Coexistence and Structural Dynamics of Redox Metal Catalysts Revealed by Operando TEM.
Sign Up to like & getrecommendations! Published in 2021 at "Advanced materials"
DOI: 10.1002/adma.202101772
Abstract: Metal catalysts play an important role in industrial redox reactions. Although extensively studied, the state of these catalysts under operating conditions is largely unknown, and assignments of active sites remain speculative. Herein, an operando transmission… read more here.
Keywords: phase; redox metal; metal catalysts; chemical dynamics ... See more keywords
A General Strategy for Open‐Flask Alkene Isomerization by Ruthenium Hydride Complexes with Non‐Redox Metal Salts
Sign Up to like & getrecommendations! Published in 2017 at "ChemCatChem"
DOI: 10.1002/cctc.201700687
Abstract: A homogenous metal hydride (M−H) catalyst for isomerization normally requires rigorous air‐free techniques. Here, we demonstrate a highly efficient protocol in which simple non‐redox metal ions as Lewis acids can promote olefin isomerization dramatically with… read more here.
Keywords: non redox; hydride; redox metal; open flask ... See more keywords
Non-redox metal ions accelerated oxygen atom transfer by Mn-Me 3 tacn complex with H 2 O 2 as oxygen resource
Sign Up to like & getrecommendations! Published in 2018 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2018.01.022
Abstract: Abstract This work demonstrates a novel strategy that the introduction of non-redox metal ions as Lewis acids to the classic dinuclear manganese complex [MnIV2(μ-O)3(Me3tacn)2](PF6)2 can greatly promote the alkene epoxidation efficiency under mild conditions with… read more here.
Keywords: redox metal; oxygen; non redox; metal ions ... See more keywords
Redox- and metal-directed structural diversification in designed metalloprotein assemblies.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02440c
Abstract: Herein we describe a designed protein building block whose self-assembly behaviour is dually gated by the redox state of disulphide bonds and the identity of exogenous metal ions. This protein construct is shown - through… read more here.
Keywords: redox metal; structural diversification; metal directed; directed structural ... See more keywords