A Redox-Relay Heck Approach to Substituted Tetrahydrofurans
Sign Up to like & getrecommendations! Published in 2023 at "Organic Letters"
DOI: 10.1021/acs.orglett.3c00769
Abstract: An operationally simple and efficient strategy for the synthesis of substituted tetrahydrofurans from readily available cis-butene-1,4-diol is described. A redox-relay Heck reaction is used to rapidly access cyclic hemiacetals that can be directly reduced to… read more here.
Keywords: redox relay; heck approach; substituted tetrahydrofurans; relay heck ... See more keywords
Paired Electrosynthesis Enabled by Hydrogen Atom Redox-Relay Strategy
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DOI: 10.1039/d4gc05715e
Abstract: Paired electrolysis is an energy- and electron-efficient approach for production of valued-added compounds at both anode and cathode. However, its synthetic generality is hindered by the need of mutually compatible... read more here.
Keywords: electrosynthesis enabled; atom redox; paired electrosynthesis; hydrogen atom ... See more keywords
External ligand-free nickel-catalyzed atom-economical coupling of isatins with allyl alcohols via a redox-relay strategy.
Sign Up to like & getrecommendations! Published in 2025 at "Chemical communications"
DOI: 10.1039/d5cc01200g
Abstract: Herein, we present a redox-relay strategy that enables the nickel-catalyzed, atom-economical coupling of isatins and allyl alcohols. This reaction is notable for its lack of requirement for additional ligands or reducing agents, and minimal catalyst… read more here.
Keywords: relay strategy; atom economical; redox relay; catalyzed atom ... See more keywords