Redox-Selective Iron Catalysis for α-Amino C-H Bond Functionalization via Aerobic Oxidation.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b03542
Abstract: Single-electron oxidation and α-deprotonation of tertiary anilines using Fe(phen)3(PF6)3 afford α-aminoalkyl radicals, which can be coupled with electrophilic partners to afford various tetrahydroquinolines. Mechanistically, the Fe(phen)n2+/3+ catalytic cycle is maintained by O2 or a TBHP… read more here.
Keywords: iron catalysis; oxidation; redox selective; iron ... See more keywords
Redox-Selective Macromolecular Electrolysis for Sequential Functionalization and Deconstruction.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c16333
Abstract: This study demonstrates that selective macromolecular electrolysis can be achieved on copolymers containing redox-orthogonal targets by controlling the externally applied voltage. We designed macromolecules containing phthalimide (E1/2 = -1.8 V vs Ag/AgNO3) and tetrachlorophthalimide (E1/2… read more here.
Keywords: redox selective; functionalization; electrolysis sequential; macromolecular electrolysis ... See more keywords