Dual-Redox-Sites Enable Two-Dimensional Conjugated Metal-Organic Frameworks with Large Pseudocapacitance and Wide Potential Window.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c03039
Abstract: Advanced supercapacitor electrodes require the development of materials with dense redox sites embedded into conductive and porous skeletons. Two-dimensional (2D) conjugated metal-organic frameworks (c-MOFs) are attractive supercapacitor electrode materials due to their high intrinsic electrical… read more here.
Keywords: dimensional conjugated; redox sites; redox; metal organic ... See more keywords
Engineering Spatially Adjacent Redox Sites with Synergistic Spin Polarization Effect to Boost Photocatalytic CO2 Methanation.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c04264
Abstract: The integration of oxidation and reduction half-reactions to amplify their synergy presents a considerable challenge in CO2 photoconversion. Addressing this challenge requires the construction of spatially adjacent redox sites while suppressing charge recombination at these… read more here.
Keywords: adjacent redox; spin polarization; spatially adjacent; redox sites ... See more keywords
Engineering spatially separated redox sites in donor-acceptor polymers for enhanced hydrogen peroxide photosynthesis.
Sign Up to like & getrecommendations! Published in 2025 at "Chemical communications"
DOI: 10.1039/d5cc04715c
Abstract: Herein, two conjugated polymers are constructed, achieving an H2O2 production rate of 6668.3 μmol g-1 h-1. The exceptional performance originates from the synergistic effect of the donor-acceptor (D-A) structure achieving spatial separation of the redox… read more here.
Keywords: redox sites; engineering spatially; spatially separated; donor acceptor ... See more keywords