Redox-triggered switching in three-dimensional covalent organic frameworks
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DOI: 10.1038/s41467-020-18588-1
Abstract: The tuning of molecular switches in solid state toward stimuli-responsive materials has attracted more and more attention in recent years. Herein, we report a switchable three-dimensional covalent organic framework (3D COF), which can undergo a… read more here.
Keywords: three dimensional; redox triggered; dimensional covalent; triggered switching ... See more keywords
Redox-triggered switch based on platinum(ii) acetylacetonate complexes bearing an isomeric donor–acceptor conjugation ligand shows a high second-order nonlinear optical response
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DOI: 10.1039/c9nj02183c
Abstract: Pt(ii) acetylcetonate complexes with an isomeric D–A ligand exhibiting exceptionally large hyperpolarizabilities are promising redox-triggered NLO switches. read more here.
Keywords: ligand; triggered switch; redox triggered; switch based ... See more keywords
Para-Substituted O-Benzyl Sulfohydroxamic Acid Derivatives as Redox-Triggered Nitroxyl (HNO) Sources
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DOI: 10.3390/molecules27165305
Abstract: Nitroxyl shows a unique biological profile compared to the gasotransmitters nitric oxide and hydrogen sulfide. Nitroxyl reacts with thiols as an electrophile, and this redox chemistry mediates much of its biological chemistry. This reactivity necessitates… read more here.
Keywords: redox triggered; substituted benzyl; chemistry; triggered nitroxyl ... See more keywords