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Reduced nucleophilicities ИBof Lewis bases B: Is ИBindependent of whether B is involved in a hydrogen bond or a halogen bond?

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3 Published in 2023 at "ChemPlusChem"

DOI: 10.1002/cplu.202300032

Abstract: Reduced nucleophilicities ИB of axially symmetric molecules B were determined from 𝐷e/𝜎min=(𝑁B/𝜎min)𝐸XY= ИB𝐸XY, where De is the equilibrium dissociation energy of the complexes BΛXY, NB is the nucleophilicity of B and EXY is the electrophilicity… read more here.

Keywords: halogen bond; terminal atom; reduced nucleophilicities; bond ... See more keywords