Vanadium‐Catalyzed Deoxydehydration of Glycerol Without an External Reductant
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DOI: 10.1002/cctc.201701049
Abstract: A vanadium‐catalysed deoxydehydration (DODH) of neat glycerol has been developed. Cheap and readily available ammonium metavanadate (NH4VO3) affords higher yields of allyl alcohol than the well‐established catalyst methyltrioxorhenium. A study in which deuterium‐labelled glycerol was… read more here.
Keywords: glycerol; vanadium catalyzed; reductant; vanadium ... See more keywords
The Nonphysiological Reductant Sodium Dithionite and [FeFe] Hydrogenase: Influence on the Enzyme Mechanism.
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DOI: 10.1021/jacs.1c07322
Abstract: [FeFe] hydrogenases are highly active enzymes for interconverting protons and electrons with hydrogen (H2). Their active site H-cluster is formed of a canonical [4Fe-4S] cluster ([4Fe-4S]H) covalently attached to a unique [2Fe] subcluster ([2Fe]H), where… read more here.
Keywords: nonphysiological reductant; mechanism; sodium dithionite; reductant sodium ... See more keywords