Synergistic combination of graphitic C3N4 and polyoxometalate-based phase-transfer catalyst for highly efficient reductant-free aerobic hydroxylation of benzene
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2017.10.083
Abstract: Abstract A facilely recyclable catalytic system towards liquid-phase reductant-free aerobic oxidation of benzene to phenol is built by simultaneously using graphitic carbon nitride (C3N4) and Ch5PMoV2. Especially, the hybrid Ch5PMoV2 is regarded as a temperature-controlled… read more here.
Keywords: phase; phase transfer; c3n4; reductant free ... See more keywords
Strategies for the Photocatalytic Generation of Carbanion Equivalents for Reductant-Free C–C Bond Formations
Sign Up to like & getrecommendations! Published in 2020 at "Accounts of Chemical Research"
DOI: 10.1021/acs.accounts.0c00620
Abstract: Conspectus The use of photocatalysis in organic chemistry has encountered a surge of novel transformations since the start of the 21st century. The majority of these transformations are driven by the generation and subsequent reaction… read more here.
Keywords: photocatalytic generation; strategies photocatalytic; carbanion; generation ... See more keywords
Nitrogen-Doped Biomass Carbons Meet with Polyoxometalates: Synergistic Catalytic Reductant-Free Aerobic Hydroxylation of Benzene to Phenol
Sign Up to like & getrecommendations! Published in 2019 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b05920
Abstract: A nitrogen-doped biomass carbon catalyst SFNC(800) was prepared by carbonizing the cheap and readily available soybean flour as the starting material at 800 °C. By combining the SFNC(800) with the Keggin-type V-containing polyoxometalate Ch5PMoV2, a… read more here.
Keywords: benzene; nitrogen doped; doped biomass; reductant free ... See more keywords
Metallic reductant-free synthesis of α-substituted propionic acid derivatives through hydrocarboxylation of alkenes with a formate salt.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc01377a
Abstract: A PGeP-pincer palladium-catalyzed hydrocarboxylation of styrenes to obtain pharmaceutically important α-arylpropionic acid derivatives was achieved using a formate salt as both a reductant and a CO2 source. The reaction was also applicable to vinylsulfone and… read more here.
Keywords: free synthesis; metallic reductant; formate salt; acid derivatives ... See more keywords