The Nonphysiological Reductant Sodium Dithionite and [FeFe] Hydrogenase: Influence on the Enzyme Mechanism.
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DOI: 10.1021/jacs.1c07322
Abstract: [FeFe] hydrogenases are highly active enzymes for interconverting protons and electrons with hydrogen (H2). Their active site H-cluster is formed of a canonical [4Fe-4S] cluster ([4Fe-4S]H) covalently attached to a unique [2Fe] subcluster ([2Fe]H), where… read more here.
Keywords: nonphysiological reductant; mechanism; sodium dithionite; reductant sodium ... See more keywords