Catalytic reduction of aryl trialkylammonium salts to aryl silanes and arenes††Electronic supplementary information (ESI) available: Experimental details and copies of NMR spectra. See DOI: 10.1039/c9sc01083a
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DOI: 10.1039/c9sc01083a
Abstract: Aryl trialkylammonium salts serve as versatile substrates for nickel-catalyzed reductions, allowing access to functionalized arenes and aryl silanes. read more here.
Keywords: catalytic reduction; aryl silanes; aryl trialkylammonium; trialkylammonium salts ... See more keywords
Ortho-Phosphinoarenesulfonamide-Mediated Staudinger Reduction of Aryl and Alkyl Azides
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DOI: 10.3390/molecules27175707
Abstract: Conventional Staudinger reductions of organic azides are sluggish with aryl or bulky aliphatic azides. In addition, Staudinger reduction usually requires a large excess of water to promote the decomposition of the aza-ylide intermediate into phosphine… read more here.
Keywords: reduction aryl; staudinger reduction; alkyl azides; reduction ... See more keywords