Reduction of Dinitrogen via 2,3'-Bipyridine-Mediated Tetraboration.
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DOI: 10.1021/jacs.0c00409
Abstract: A new molecular system for nitrogen reduction, involving a 2,3'-bipyridine-anchored, end-on-bridging dinitrogen complex of the Me2B-BMe2 intermediate (4), has been explored by theoretical methods. The 2,3'-bipyridine-mediated cleavage of the Bsp3-Bsp3 bond in 4 may lead… read more here.
Keywords: dinitrogen; bipyridine; dinitrogen via; bipyridine mediated ... See more keywords
Revisiting amorphous molybdenum sulfide's activity for the electro-driven reduction of dinitrogen and N-containing substrates.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc05078d
Abstract: Ammonia (NH3) is a major feedstock of the chemical industry. The imperious need to decarbonize its production has stimulated a quest for efficient catalysts able to drive the direct electro-reduction of dinitrogen (N2) into NH3.… read more here.
Keywords: reduction; molybdenum sulfide; amorphous molybdenum; reduction dinitrogen ... See more keywords