Carbon dioxide reduction by an Al–O–P frustrated Lewis pair
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DOI: 10.1039/d2sc01870e
Abstract: The reaction of tBu2P(O)H with Bis2AlH (Bis = CH(SiMe3)2) afforded the adduct tBu2P(H)–O–Al(H)Bis2 (3). It slowly releases H2 to form the first oxygen-bridged geminal Al/P frustrated Lewis pair tBu2P–O–AlBis2. It is capable of reversibly binding… read more here.
Keywords: lewis pair; frustrated lewis; carbon dioxide; reduction frustrated ... See more keywords