Enantioselective metal-free reduction of ketones by a user-friendly silane with a reusable chiral additive
Sign Up to like & getrecommendations! Published in 2018 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2018.06.032
Abstract: Abstract 1-Hydrosilatrane, a safe and easy-to-handle reducing reagent that can be inexpensively accessed, has been shown to reduce prochiral ketones asymmetrically in the presence of chiral 1,2-aminoalcohols with ees ranging from 8% to 86%. The… read more here.
Keywords: free reduction; enantioselective metal; reduction ketones; user friendly ... See more keywords
Electrochemical deoxygenative reduction of ketones.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04548f
Abstract: Electrochemical reduction via paired electrolysis has been used to achieve deoxygenative reduction of ketones. As a result of the complexing of ketones with the triphenylphosphine radical cation generated by anodic oxidation, the reduction of carbonyl… read more here.
Keywords: reduction; deoxygenative reduction; reduction ketones; electrochemical deoxygenative ... See more keywords