Theoretical research on heterogeneous reduction of N2O by char
Sign Up to like & getrecommendations! Published in 2017 at "Applied Thermal Engineering"
DOI: 10.1016/j.applthermaleng.2017.07.166
Abstract: Abstract In order to investigate heterogeneous reduction of N2O by char, quantum chemistry theoretical calculation based on zigzag and armchair char edge model was conducted. Thermodynamics and kinetics calculation were carried out combined with density… read more here.
Keywords: n2o char; char; char edge; heterogeneous reduction ... See more keywords
NO Reduction to N2O Triggered by a Dinuclear Dinitrosyl Iron Complex via the Associated Pathways of Hyponitrite Formation and NO Disproportionation.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00541
Abstract: In spite of the comprehensive study of the metal-mediated conversion of NO to N2O disclosing the conceivable processes/mechanism in biological and biomimetic studies, in this study, the synthesis cycles and mechanism of NO reduction to… read more here.
Keywords: formation; bdmap; n2o triggered; reduction n2o ... See more keywords
Direct Reduction of NO to N2O by a Mononuclear Nonheme Thiolate Ligated Iron(II) Complex via Formation of a Metastable {FeNO}7 Complex.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02383
Abstract: Addition of NO to a nonheme dithiolate-ligated iron(II) complex, FeII(Me3TACN)(S2SiMe2) (1), results in the generation of N2O. Low-temperature spectroscopic studies reveal a metastable six-coordinate {FeNO}7 intermediate (S = 3/2) that was trapped at -135 °C… read more here.
Keywords: thiolate ligated; ligated iron; reduction n2o; iron complex ... See more keywords
Reduction of N2O with hydrosilanes catalysed by RuSNS nanoparticles.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc01470j
Abstract: A series of RuSNS nanoparticles, prepared by decomposition of Ru(COD)(COT) with H2 in the presence of an SNS ligand, have been found to catalyse the reduction of the greenhouse gas N2O to N2 employing different… read more here.
Keywords: hydrosilanes catalysed; reduction n2o; catalysed rusns; rusns nanoparticles ... See more keywords
Si-doped C3N monolayers as efficient single-atom catalysts for the reduction of N2O: a computational study
Sign Up to like & getrecommendations! Published in 2020 at "Molecular Physics"
DOI: 10.1080/00268976.2020.1759830
Abstract: Density functional theory calculations are performed to probe reaction pathways of N2O reduction by CO molecule catalysed over Si-doped C3N (Si-C3N) nanosheets. According to our results, a single Si atom can be stabilised above the… read more here.
Keywords: atom; reduction; c3n monolayers; single atom ... See more keywords