Reduction of Nitroarenes Using Efficient PdRu@mSiO2 Nanocatalyst Synthesized by a One‐Pot Approach
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Materials Interfaces"
DOI: 10.1002/admi.202400055
Abstract: In the present work, PdRu@mSiO2 bimetallic core‐shell nanoreactors (NRs) are synthesized for the first time by a fine‐tuning one‐pot method. The obtained NRs are evaluated in the reduction of nitroarenes using 4‐nitrophenol (4‐NP), 1‐chloro‐4‐nitrobenzene (1‐Cl‐4‐NB),… read more here.
Keywords: one pot; pdru msio2; nitroarenes using; reduction nitroarenes ... See more keywords
Designing a Polyoxometalate-Incorporated Metal-Organic Framework for Reduction of Nitroarenes to Anilines by Sequential Proton-Coupled Electron Transfers.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00106
Abstract: Developing new photocatalysts for reduction of nitroarenes to anilines under mild conditions is very significant. Herein, a new polyoxometalate-based metal-organic framework (POMOF), {[Co(H2O)]2[Co2(H2O)6(TPT)][Co(TPT)PW11O39]}·3H2O·TPT (namely, CoW-TPT, TPT = 2,4,6-tri(4-pyridyl)-1,3,5-triazine), was prepared by incorporating Co(II)-substituted Keggin-type anions… read more here.
Keywords: framework; tpt; electron; nitroarenes anilines ... See more keywords
Metal-Free Chemoselective Reduction of Nitroarenes Catalyzed by Covalent Triazine Frameworks: The Role of Embedded Heteroatoms.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c01091
Abstract: Chemoselective reduction of nitroarenes to arylamines is a core technology for the synthesis of numerous chemicals. The technology, however, relies on applying precious noble metal catalysts. We present our findings on the development of robust… read more here.
Keywords: metal free; triazine frameworks; covalent triazine; chemoselective reduction ... See more keywords
In situ decoration of Pd NPs over methotrexate encapsulated CoFe2O4 as a recyclable catalyst for the reduction of nitroarenes and synthesis of diaryl sulfide derivatives
Sign Up to like & getrecommendations! Published in 2025 at "Scientific Reports"
DOI: 10.1038/s41598-025-12436-2
Abstract: This study presents the successful immobilization of a methotrexate-palladium complex onto the surface of magnetic CoFe2O4 nanoparticles through a simple and cost-efficient process. The environmentally friendly heterogeneous catalyst was comprehensively characterized using thermogravimetric analysis (TGA),… read more here.
Keywords: spectroscopy; catalyst; synthesis; diaryl sulfide ... See more keywords
Nitrogen-enriched carbon nanotube supported palladium as a catalyst for desulfurization of dibenzothiophene and reduction of nitroarenes
Sign Up to like & getrecommendations! Published in 2025 at "Scientific Reports"
DOI: 10.1038/s41598-025-88211-0
Abstract: In this study, a new nitrogen-enriched multiwall carbon nanotube is prepared and utilized to stabilize palladium species. After the characterization of this new composite, it was applied as a catalyst in the reduction of nitroarenes… read more here.
Keywords: catalyst; carbon nanotube; dibenzothiophene; reduction ... See more keywords
Ultra-small iridium nanoparticles as active catalysts for the selective and efficient reduction of nitroarenes
Sign Up to like & getrecommendations! Published in 2020 at "New Journal of Chemistry"
DOI: 10.1039/d0nj03621h
Abstract: Ultra-small noble metal iridium nanoparticles (IrNPs) possessing superior catalytic activity were prepared using tannin as a stabilizer via a controlled one-step synthesis. Their average size was about 3.5 ± 0.5 nm, and they were enclosed… read more here.
Keywords: catalytic reduction; reduction; iridium nanoparticles; reduction nitroarenes ... See more keywords
Cobalt catalyzed chemoselective reduction of nitroarenes: hydrosilylation under thermal and photochemical reaction conditions.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00328k
Abstract: Commercially available Co2(CO)8 was used as an effective catalyst for the hydrosilylation of nitroarenes under both thermal and photochemical conditions. A wide variety of nitroarenes with various functionalities were selectively reduced to aromatic amines. Syntheses… read more here.
Keywords: cobalt catalyzed; catalyzed chemoselective; hydrosilylation; chemoselective reduction ... See more keywords