Biocatalytic reduction of α,β-unsaturated carboxylic acids to allylic alcohols
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DOI: 10.1039/d0gc00867b
Abstract: We have developed robust in vivo and in vitro biocatalytic systems that enable reduction of α,β-unsaturated carboxylic acids to allylic alcohols and their saturated analogues. These compounds are prevalent scaffolds in many industrial chemicals and… read more here.
Keywords: acids allylic; carboxylic acids; allylic alcohols; reduction unsaturated ... See more keywords
Enantioselective Meerwein-Ponndorf-Verley Reduction of β,γ-Unsaturated α-Keto Esters by Asymmetric Binary-Acid Catalysis in Green Solvent iPrOH
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DOI: 10.1039/d2gc03441g
Abstract: Enantioselective Meerwein-Ponndorf-Verley reduction of β,γ-unsaturated α-keto esters in iPrOH alone was achieved by using asymmetric binary-acid catalysts. The presence of 0.2 mol% of a chiral phosphoric acid and 0.5 mol%... read more here.
Keywords: enantioselective meerwein; reduction unsaturated; ponndorf verley; acid ... See more keywords
Thermodynamics Evaluation of Selective Hydride Reduction for α,β-Unsaturated Carbonyl Compounds
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DOI: 10.3390/molecules28062862
Abstract: The selective reduction of α,β-unsaturated carbonyl compounds is one of the core reactions and also a difficult task for organic synthesis. We have been attempting to study the thermodynamic data of these compounds to create… read more here.
Keywords: unsaturated carbonyl; reduction unsaturated; thermodynamics; carbonyl compounds ... See more keywords