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Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc00933j
Abstract: Aerobic epoxidation of olefins catalyzed by iron complexes without the use of a sacrificial coreductant is unknown. We report the reductive activation of O2 by a bioinspired [(bTAML)FeIII(H2O)]- (1) complex to catalyze the epoxidation of…
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Keywords:
activation bioinspired;
reductive activation;
bioinspired complex;
epoxidation ... See more keywords
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Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04841h
Abstract: An extremely bulky xanthene bridged diamide ligand (TCHPNON = 4,5-bis(2,4,6-tricyclohexylanilido)-2,7-diethyl-9,9-dimethyl-xanthene) has been developed and used to prepare two monomeric diamido-calcium complexes [(TCHPNON)Ca(D)n] (D = THF, n = 2, 3; D = toluene, n = 1,…
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Keywords:
calcium;
extremely bulky;
activation using;
reductive activation ... See more keywords